Abstract

This dcoument specifies a method for the determination of fluoro-, chloro-, bromo- and iodo-organic compounds (AOF, AOCl, AOBr, AOI). Due to the high solubility of AgF in water the scope of ISO 9562 is restricted to Cl-, Br- and I-organic compounds (AOX, calculated as chlorine) because of the applied argentometric detection. The PN follows the proven AOX ISO 9562 method: adsorption of organohalogen compounds on activated carbon, oxidative combustion at 1000 °C with following alterations: constant water feed during combustion (hydropyrolysis), absorption of combustion gases in water, halide specific detection using ionchromatography. The method is applicable for the determination of 2 µg/l AOF, expressed as F 10 µg/l AOCl, expressed as Cl 1 µg/l AOBr, expressed as Br 1 µg/l AOI, expressed as I. Samples for determination of AOF are treated differently than samples for the determination of AOCl, AOBr and AOI. - Samples for determination of AOF are not acidified. The adsorption takes place under unchanged pH conditions. Washing is also performed with a neutral washing solution. - Samples for the determination of AOCl, AOBr and AOI are adjusted to a pH value 2 with nitric acid, the adsorption and washing take place in a nitric acid environment.

Begin

2023-05-11

WI

00230430

Planned document number

DIN EN ISO 18127

Project number

11904878

Responsible national committee

NA 119-01-03-01-12 AK - Ion chromatographic methods (ISO/TC 147/SC 2/WG 33)  

Responsible european committee

CEN/TC 230/WG 1 - Physical and biochemical methods  

Responsible international committee

ISO/TC 147/SC 2/WG 33 - Ion chromatography methods  

draft standard

Water quality - Determination of adsorbable organically bound fluorine, chlorine, bromine and iodine (AOF, AOCl, AOBr, AOI) - Method using combustion and subsequent ion chromatographic measurement (ISO/DIS 18127:2024); German and English version prEN ISO 18127:2024
2024-08
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previous edition(s)

German standard methods for the examination of water, waste water and sludge - Parameters characterizing effects and substances (group H) - Part 59: Determination of adsorbable organically bound fluorine, chlorine, bromine and iodine (AOF, AOCl, AOBr, AOI) using combustion and subsequent ion chromatographic measurement (H 59)
2022-10

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